ΔE 14.6, fair: the same colour family, but not a straight swap. Purple Shadow is a little darker, more muted, warmer than Pale Violet Red.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 15). Purple Shadow is a little darker, more muted, warmer than Pale Violet Red.
The same difference applies the other way round: Pale Violet Red is a little lighter, more saturated, cooler.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Pale Violet Red on the colour wheel See Purple Shadow on the colour wheel
All matches: Pale Violet Red equivalents · Purple Shadow equivalents