ΔE 10.5, fair: the same colour family, but not a straight swap. Purple Shadow is a little darker, cooler than Chestnut Brown.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 10). Purple Shadow is a little darker, cooler than Chestnut Brown.
The same difference applies the other way round: Chestnut Brown is a little lighter, warmer.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Chestnut Brown on the colour wheel See Purple Shadow on the colour wheel
All matches: Chestnut Brown equivalents · Purple Shadow equivalents