ΔE 14.1, fair: the same colour family, but not a straight swap. Pastel Yellow is noticeably lighter, more muted than Poison Yellow. They are different kinds of paint: AMMO by Mig Poison Yellow is an opaque base/layer paint and Army Painter Pastel Yellow is a one-coat contrast-style paint, so they won’t behave the same on the model even where the colour is close.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 14). Pastel Yellow is noticeably lighter, more muted than Poison Yellow. They are different kinds of paint.
The same difference applies the other way round: Poison Yellow is noticeably darker, more saturated.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Poison Yellow on the colour wheel See Pastel Yellow on the colour wheel
All matches: Poison Yellow equivalents · Pastel Yellow equivalents