ΔE 14.2, fair: the same colour family, but not a straight swap. Dark Red is a little darker, much more saturated, cooler than Flat Brown.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 14). Dark Red is a little darker, much more saturated, cooler than Flat Brown.
The same difference applies the other way round: Flat Brown is a little lighter, much more muted, warmer.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Flat Brown on the colour wheel See Dark Red on the colour wheel
All matches: Flat Brown equivalents · Dark Red equivalents