ΔE 11.8, fair: the same colour family, but not a straight swap. Brass is a little darker, more saturated than Dark Iron.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 12). Brass is a little darker, more saturated than Dark Iron.
The same difference applies the other way round: Dark Iron is a little lighter, more muted.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Dark Iron on the colour wheel See Brass on the colour wheel
All matches: Dark Iron equivalents · Brass equivalents