Brilli White vs Rust

How close are they?

ΔE 64.4, loose: different enough that you should pick on purpose. Rust is noticeably darker, more saturated than Brilli White.

Can I use Rust instead of Brilli White?

Not as a straight swap; see the closer alternatives below. Loose match (ΔE 64). Rust is noticeably darker, more saturated than Brilli White.

Can I use Brilli White instead of Rust?

The same difference applies the other way round: Brilli White is noticeably lighter, more muted.

ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.