Desert Khaki vs Dark Yellow

How close are they?

ΔE 15.2, loose: different enough that you should pick on purpose. Dark Yellow is noticeably darker, cooler than Desert Khaki.

Can I use Dark Yellow instead of Desert Khaki?

Not as a straight swap; see the closer alternatives below. Loose match (ΔE 15). Dark Yellow is noticeably darker, cooler than Desert Khaki.

Can I use Desert Khaki instead of Dark Yellow?

The same difference applies the other way round: Desert Khaki is noticeably lighter, warmer.

ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.