ΔE 10.5, fair: the same colour family, but not a straight swap. Obsidian Black is noticeably lighter than Old Brass.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 11). Obsidian Black is noticeably lighter than Old Brass.
The same difference applies the other way round: Old Brass is noticeably darker.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Old Brass on the colour wheel See Obsidian Black on the colour wheel
All matches: Old Brass equivalents · Obsidian Black equivalents