ΔE 13.7, fair: the same colour family, but not a straight swap. Purple Shadow is a little lighter, more saturated, cooler than Oxide Brown Dark.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 14). Purple Shadow is a little lighter, more saturated, cooler than Oxide Brown Dark.
The same difference applies the other way round: Oxide Brown Dark is a little darker, more muted, warmer.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Oxide Brown Dark on the colour wheel See Purple Shadow on the colour wheel
All matches: Oxide Brown Dark equivalents · Purple Shadow equivalents