ΔE 21.2, loose: different enough that you should pick on purpose. Azure is noticeably lighter, cooler than Ultramar Blue.
Not as a straight swap; see the closer alternatives below. Loose match (ΔE 21). Azure is noticeably lighter, cooler than Ultramar Blue.
The same difference applies the other way round: Ultramar Blue is noticeably darker, warmer.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Ultramar Blue on the colour wheel See Azure on the colour wheel
All matches: Ultramar Blue equivalents · Azure equivalents