ΔE 9.7, close: similar, with a visible difference side by side. Highlight Skin is a little darker, more saturated than Titanium White.
Usually, if you are not matching paint already on the model. Close match (ΔE 10). Highlight Skin is a little darker, more saturated than Titanium White.
The same difference applies the other way round: Titanium White is a little lighter, more muted.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Titanium White on the colour wheel See Highlight Skin on the colour wheel
All matches: Titanium White equivalents · Highlight Skin equivalents