ΔE 6.7, close: similar, with a visible difference side by side. Polished Silver is a little darker than Necron Compound.
Usually, if you are not matching paint already on the model. Close match (ΔE 7). Polished Silver is a little darker than Necron Compound.
The same difference applies the other way round: Necron Compound is a little lighter.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Necron Compound on the colour wheel See Polished Silver on the colour wheel
All matches: Necron Compound equivalents · Polished Silver equivalents