ΔE 9.7, close: similar, with a visible difference side by side. Phthalo Blue RS is more saturated, cooler than Naggaroth Night.
Usually, if you are not matching paint already on the model. Close match (ΔE 10). Phthalo Blue RS is more saturated, cooler than Naggaroth Night.
The same difference applies the other way round: Naggaroth Night is more muted, warmer.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Naggaroth Night on the colour wheel See Phthalo Blue RS on the colour wheel
All matches: Naggaroth Night equivalents · Phthalo Blue RS equivalents