ΔE 14.7, fair: the same colour family, but not a straight swap. Pyrrole Orange is much more saturated than Magmadroth Flame. They are different kinds of paint: Citadel Magmadroth Flame is a one-coat contrast-style paint and Golden Pyrrole Orange is an ink, glaze or transparent paint, so they won’t behave the same on the model even where the colour is close.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 15). Pyrrole Orange is much more saturated than Magmadroth Flame. They are different kinds of paint.
The same difference applies the other way round: Magmadroth Flame is much more muted.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Magmadroth Flame on the colour wheel See Pyrrole Orange on the colour wheel
All matches: Magmadroth Flame equivalents · Pyrrole Orange equivalents