Iron Warriors vs Dark Elder Bronze

How close are they?

ΔE 19.7, loose: different enough that you should pick on purpose. Dark Elder Bronze is noticeably darker, more saturated than Iron Warriors.

Can I use Dark Elder Bronze instead of Iron Warriors?

Not as a straight swap; see the closer alternatives below. Loose match (ΔE 20). Dark Elder Bronze is noticeably darker, more saturated than Iron Warriors.

Can I use Iron Warriors instead of Dark Elder Bronze?

The same difference applies the other way round: Iron Warriors is noticeably lighter, more muted.

ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.