Averland Sunset vs Ember Orange

How close are they?

ΔE 21.7, loose: different enough that you should pick on purpose. Ember Orange is noticeably darker, more muted, warmer than Averland Sunset.

Can I use Ember Orange instead of Averland Sunset?

Not as a straight swap; see the closer alternatives below. Loose match (ΔE 22). Ember Orange is noticeably darker, more muted, warmer than Averland Sunset.

Can I use Averland Sunset instead of Ember Orange?

The same difference applies the other way round: Averland Sunset is noticeably lighter, more saturated, cooler.

ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.