Witchbane Plum vs Dioxazine Violet

How close are they?

ΔE 23.2, loose: different enough that you should pick on purpose. Dioxazine Violet is a little darker, cooler than Witchbane Plum.

Can I use Dioxazine Violet instead of Witchbane Plum?

Not as a straight swap; see the closer alternatives below. Loose match (ΔE 23). Dioxazine Violet is a little darker, cooler than Witchbane Plum.

Can I use Witchbane Plum instead of Dioxazine Violet?

The same difference applies the other way round: Witchbane Plum is a little lighter, warmer.

ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.