ΔE 6.1, close: similar, with a visible difference side by side. Navy Blue is a little darker, more saturated than Ultramarine Blue.
Usually, if you are not matching paint already on the model. Close match (ΔE 6). Navy Blue is a little darker, more saturated than Ultramarine Blue.
The same difference applies the other way round: Ultramarine Blue is a little lighter, more muted.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Ultramarine Blue on the colour wheel See Navy Blue on the colour wheel
All matches: Ultramarine Blue equivalents · Navy Blue equivalents