ΔE 7.4, close: similar, with a visible difference side by side. Prussian Blue is a little darker, warmer than Twilight Sky.
Usually, if you are not matching paint already on the model. Close match (ΔE 7). Prussian Blue is a little darker, warmer than Twilight Sky.
The same difference applies the other way round: Twilight Sky is a little lighter, cooler.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Twilight Sky on the colour wheel See Prussian Blue on the colour wheel
All matches: Twilight Sky equivalents · Prussian Blue equivalents