Red Copper vs Coppery Orange

How close are they?

ΔE 23.2, loose: different enough that you should pick on purpose. Coppery Orange is noticeably lighter, much more muted, warmer than Red Copper.

Can I use Coppery Orange instead of Red Copper?

Not as a straight swap; see the closer alternatives below. Loose match (ΔE 23). Coppery Orange is noticeably lighter, much more muted, warmer than Red Copper.

Can I use Red Copper instead of Coppery Orange?

The same difference applies the other way round: Red Copper is noticeably darker, much more saturated, cooler.

ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.