ΔE 6.5, close: similar, with a visible difference side by side. Scorched Wood is more saturated than Matt Black Primer. They are different kinds of paint: Army Painter Matt Black Primer is a technical paint or medium and Green Stuff World Scorched Wood is an opaque base/layer paint, so they won’t behave the same on the model even where the colour is close.
Usually, if you are not matching paint already on the model. Close match (ΔE 6). Scorched Wood is more saturated than Matt Black Primer. They are different kinds of paint.
The same difference applies the other way round: Matt Black Primer is more muted.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Matt Black Primer on the colour wheel See Scorched Wood on the colour wheel
All matches: Matt Black Primer equivalents · Scorched Wood equivalents