Grim Black vs Cygor Brown

How close are they?

ΔE 33.2, loose: different enough that you should pick on purpose. Cygor Brown is noticeably lighter, much more saturated than Grim Black.

Can I use Cygor Brown instead of Grim Black?

Not as a straight swap; see the closer alternatives below. Loose match (ΔE 33). Cygor Brown is noticeably lighter, much more saturated than Grim Black.

Can I use Grim Black instead of Cygor Brown?

The same difference applies the other way round: Grim Black is noticeably darker, much more muted.

ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.