ΔE 12.9, fair: the same colour family, but not a straight swap. Ember Orange is noticeably lighter, more saturated than Fiery Vermilion.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 13). Ember Orange is noticeably lighter, more saturated than Fiery Vermilion.
The same difference applies the other way round: Fiery Vermilion is noticeably darker, more muted.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Fiery Vermilion on the colour wheel See Ember Orange on the colour wheel
All matches: Fiery Vermilion equivalents · Ember Orange equivalents