ΔE 7.7, close: similar, with a visible difference side by side. Dark Navy Blue is a little darker, more muted, warmer than Dark Sky.
Usually, if you are not matching paint already on the model. Close match (ΔE 8). Dark Navy Blue is a little darker, more muted, warmer than Dark Sky.
The same difference applies the other way round: Dark Sky is a little lighter, more saturated, cooler.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Dark Sky on the colour wheel See Dark Navy Blue on the colour wheel
All matches: Dark Sky equivalents · Dark Navy Blue equivalents