ΔE 15.3, loose: different enough that you should pick on purpose. Prussian Blue Hue is noticeably lighter, cooler than Dark Blue Tone. They are different kinds of paint: Army Painter Dark Blue Tone is a wash/shade and Golden Prussian Blue Hue is an ink, glaze or transparent paint, so they won’t behave the same on the model even where the colour is close.
Not as a straight swap; see the closer alternatives below. Loose match (ΔE 15). Prussian Blue Hue is noticeably lighter, cooler than Dark Blue Tone. They are different kinds of paint.
The same difference applies the other way round: Dark Blue Tone is noticeably darker, warmer.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Dark Blue Tone on the colour wheel See Prussian Blue Hue on the colour wheel
All matches: Dark Blue Tone equivalents · Prussian Blue Hue equivalents