Caribbean Ocean vs Dark Green Blue

How close are they?

ΔE 38.6, loose: different enough that you should pick on purpose. Dark Green Blue is noticeably darker, much more muted than Caribbean Ocean.

Can I use Dark Green Blue instead of Caribbean Ocean?

Not as a straight swap; see the closer alternatives below. Loose match (ΔE 39). Dark Green Blue is noticeably darker, much more muted than Caribbean Ocean.

Can I use Caribbean Ocean instead of Dark Green Blue?

The same difference applies the other way round: Caribbean Ocean is noticeably lighter, much more saturated.

ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.