ΔE 14.7, fair: the same colour family, but not a straight swap. Imperium Blue is noticeably darker, more saturated, cooler than Alien Purple.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 15). Imperium Blue is noticeably darker, more saturated, cooler than Alien Purple.
The same difference applies the other way round: Alien Purple is noticeably lighter, more muted, warmer.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Alien Purple on the colour wheel See Imperium Blue on the colour wheel
All matches: Alien Purple equivalents · Imperium Blue equivalents