ΔE 8.4, close: similar, with a visible difference side by side. Radiation Glow is a little lighter, more saturated than Orange. They are different kinds of paint: AMMO by Mig Orange is an ink, glaze or transparent paint and Army Painter Radiation Glow is an opaque base/layer paint, so they won’t behave the same on the model even where the colour is close.
Usually, if you are not matching paint already on the model. Close match (ΔE 8). Radiation Glow is a little lighter, more saturated than Orange. They are different kinds of paint.
The same difference applies the other way round: Orange is a little darker, more muted.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Orange on the colour wheel See Radiation Glow on the colour wheel
All matches: Orange equivalents · Radiation Glow equivalents