ΔE 11.4, fair: the same colour family, but not a straight swap. Hardened Leather is a little lighter than Leather Brown. They are different kinds of paint: AMMO by Mig Leather Brown is an opaque base/layer paint and Army Painter Hardened Leather is a one-coat contrast-style paint, so they won’t behave the same on the model even where the colour is close.
Only where an exact match doesn’t matter, such as a new unit or a highlight. Fair match (ΔE 11). Hardened Leather is a little lighter than Leather Brown. They are different kinds of paint.
The same difference applies the other way round: Leather Brown is a little darker.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Leather Brown on the colour wheel See Hardened Leather on the colour wheel
All matches: Leather Brown equivalents · Hardened Leather equivalents