ΔE 9.7, close: similar, with a visible difference side by side. Buff is a little lighter, more saturated than Khaki.
Usually, if you are not matching paint already on the model. Close match (ΔE 10). Buff is a little lighter, more saturated than Khaki.
The same difference applies the other way round: Khaki is a little darker, more muted.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Khaki on the colour wheel See Buff on the colour wheel
All matches: Khaki equivalents · Buff equivalents