ΔE 8.5, close: similar, with a visible difference side by side. Purple Shadow is a little lighter, more saturated, cooler than Coffee Brown.
Usually, if you are not matching paint already on the model. Close match (ΔE 9). Purple Shadow is a little lighter, more saturated, cooler than Coffee Brown.
The same difference applies the other way round: Coffee Brown is a little darker, more muted, warmer.
ΔE is the colour difference between our two swatch estimates: under about 6 is close, over about 15 is loose. Real paints also differ in finish, coverage and how they thin, so test before you commit.
See Coffee Brown on the colour wheel See Purple Shadow on the colour wheel
All matches: Coffee Brown equivalents · Purple Shadow equivalents